Colón have the chance to establish an early hold at the top of Group A against an Argentinos Juniors side who have produced some high-scoring wins.
Barracas Central look to create a major upset against a Talleres side who sit near the top of Group A in Copa de la Liga Profesional.
Racing sit near the top of Group B but could face a tough challenge from Godoy Cruz, who have been hard to beat in Copa de la Liga Profesional.
Atlético Tucumán have one of the lowest-scoring offenses in Copa de la Liga Profesional but take on Arsenal, who boast one of the leakiest defenses.
Sarmiento clash with Belgrano, with a win enough to see either team go top of the table depending on results elsewhere in Group B.
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