Jacques and Mira might look like models, but their marriage is far from picture-perfect. After six years, they've decided to call it quits, and they bring in Vikki to guide them through the mediation process. When it comes to their marital assets, these two are anything but Zen, so they need Vikki's help to decide who walks away with a giant Buddha head, an apartment in Paris, and a diamond ring. Nothing takes the shine out of a diamond like divorce, and Vikki faces some resistance at the beginning. However, Vikki isn't rattled and gets right down to business doling out their stuff.

After 13 years, Jennifer and Golan haven't been very lucky in love and have decided to call Vikki to help end their marriage and divide their assets. Golan ran his business into the ground and just wants to have fun, leaving Jennifer to bring home the bacon. Jennifer, on the other hand, is desperate to sell all their assets and move on. These two are stuck in a real crisis and are clinging to a historically significant antique passport, a diamond necklace, a painting by a famous artist, and five income-producing properties. However, despite Vikki's peacekeeping efforts, Golan might be one of Vikki’s greatest mediation challenges ever.

After returning from a tour of duty in Iraq, Tim wasn't the same person Kelly fell in love with, and his PTSD issues have taken a heavy toll on their marriage. Although neither really wants to be divorced, Kelly is ready to go AWOL, so they've called Vikki to help divide and appraise their assets. The couple is shocked when they hear how much their stuff is really worth.

After 26 years of marriage, Emily and Dave have come to a crossroads. As Vikki tries to determine a fair distribution of assets and gets to know this couple better, she decides they may not be ready to divorce and shifts from mediating their assets to negotiating a last ditch effort to save their marriage.

Krissy and Tina have spent 11 years together. However, soon after building their dream home, their marriage hit the rocks when Krissy and Tina became Krissy and Tina and Amy. Now Vikki is the newest lady in their lives, and she's ready to mediate the division of their home, their cars, a collection of t-shirts, and their two dogs. Vikki's about to lay down the law but when all is said and done, she could be the one who ends up in the dog house.

Stuart and Iret have decided it's time to end their marriage after 26 years. Stuart spent his life on the road as a wedding couture salesman, making other people’s wedding dreams come true, while his own marriage hit the rocks and became a nightmare. They've been pitching insults back and forth over a baseball card collection, their home, a photograph, and a Judaica collection. It's going to take a miracle for Vikki to determine a fair settlement and distribute their most prized possessions.