Ten men and women gather for the first time in "Love Catcher" to play the game where they show their first impression and try to distinguish between a love catcher and a money catcher. The Watchers begin their guesses as well.

Suspicions grow after the number of lover catchers and money catchers are revealed; as a part of the challenge, the couples go for a photo shoot together to get to know each other more.

Choim is annoyed by Jiyeon and Chaeun. Meanwhile, everyone suspects Jiyeon to be a money catcher, but soon important clues about their identities are exposed to advance the game.

The fourth game's mission is to make couple rings; Minho makes people suspect Jiyeon more; Choim is constantly annoyed by Jiyeon and Chaeun, hence she forms allies with Seonga.

Chaeun is worried about Jiyeon who cried in front of Seungu, while Choim is disappointed. The fifth challenge is to head to the shopping mall and set up an outfit for the male partners.

Choim and Seonga are awkward after the voting; the couples go camping; after seeing Seonga crying alone in the bathroom, Choim becomes confused.