Release Me chronicles the story of Texas killer Kenneth Allen McDuff who received the death sentence in 1966 for a murderous rampage that left three teen-agers dead. He was paroled years later only to kill again. His subsequent recapture and trial resulted in another death sentence, carried out in 1998.

Pride and Joy focuses on Eric Napoletano who brutally murdered his victims, including his wife Myra. Protected by a mother, who worked for the New York City Police Department, Napoletano eluded the law from New York to Albuquerque, New Mexico before he was finally arrested on March 27, 1991. A New Jersey prosecutor coordinated a multi-jurisdictional investigation and secured two murder convictions and two consecutive life terms in prison for the killer, who is currently in the New Jersey State Prison in Trenton. This episode recounts the cooperative efforts of law enforcement agencies to catch this serial killer and the challenges the Clifton, New Jersey prosecutors faced when seeking to put him away for life.

Young Love tells the story of a high school student whose overpowering obsession for his girlfriend led him to murder a rival for her affections in the parking lot of their high school in Fayetteville, Tennessee. The alleged killer, Jacob Davis, was an honor student involved in the drama club at his high school. The victim was a football player. The shooting shocked the small Tennessee town. The prosecution's task was to dismantle the defense's argument that the shooter was acting under a diminished mental capacity and to prove to a jury that his act was premeditated.

This is the story of two young men whose paths tragically crossed on September 29, 1998 in Houston, Texas. One was a sheriff's deputy while the other, like his father, stayed on the wrong side of the law. The deputy made a routine traffic stop one night that ended with him being brutally shot to death by the other young man, Michael Lopez. Prosecutors argued that 17-year-old Lopez deserved to die, but would the jury agree?

This episode recounts a heinous crime that is every parent's nightmare, the death of a child. On an autumn evening in November 1998, a man randomly killed a 9-year-old boy in a public bathroom in southern California. The little boy was only feet away and within earshot of his young cousins, relatives and Mother. The murderer was captured days later as he tried to kill again, prompting a startling courtroom confession and an insanity defense. For his crimes, San Diego County prosecutors argued that he deserved to be put on death row. This episode is the story of the killer's monstrous acts and the prosecution team that fought to bring him to justice.

The Green Widow focuses on Mary Ellen Samuels, a woman whose lust for money and drugs led her to arrange for the 1988 murder of her husband, a successful Hollywood cameraman. Worried that authorities were catching up to her, she also arranged for the murder of the hit man.