Before a night out in Cusco with Miss Peru, Shay heads deep into the Sacred Valley with adventure photographer Mariano Breccia to explore two Incan favorites: coca tea and a corn beer called chichi de jora. A world-class mixology duo takes Shay to the source of their secret ingredient before introducing her to a local agronomist making wines from an unlikely crop.

Shay Mitchell stops by Buenos Aires' first tiki bar, where flaming cocktails kick off an all-nighter. A visit to the birthplace of Argentine pizza fuels a trip to the countryside, where Shay sips maté with a charismatic Gaucho before attempting to corral a herd of cattle. Then, a wine tasting transports Shay to all four corners of the country, and world-famous mixologist Federico Cuco performs spirit magic passed down from ancient traditions. A rainy day inspires Shay to investigate Argentina's obsession with Fernet Branca before searching for a hidden restaurant where a renowned chef never repeats a menu. Finally, a last-minute excursion has Shay sneaking off for one final drink before her plane leaves town.

Shay Mitchell heads to the island of Florianopolis, where social media maven, Camilla Coutinho, reveals how locals unwind. Following a night of caipirinhas and cachaça shots, a rigorous pint tasting at a local craft brewery leads to an unexpected proposal. After a precarious drive, Shay seeks a surefire hangover cure involving an açai smoothie and a ride on the big waves of Praia Mole beach with pro surfer Karina Abras. Shay nurses her wipeout wounds with a dinner at Ostradamus, where a table on the water serves up native wine and the freshest oysters in the country. Finally, a day trip to Brazil's only organic cachaça distillery puts Shay to work chopping sugarcane in the middle of the Atlantic Forest.