In the first episode of "NYC Prep," seniors Jessie and PC establish themselves as the King and Queen of the NYC prep school scene. Sharp and sassy, the pair cast a cruel eye on the rest of the city as they hit New York’s most exclusive spots. Since they used to be an item, Jessie gets tense every time PC looks for a new girl. Jessie isn’t quite sure if she wants to be with PC, but definitely doesn’t want anyone else to have him either! Camille is the prim and proper prep school junior, but is her obsession with Harvard killing her social life? Further uptown, prep school junior Kelli is living the dream with her own apartment in New York City, which means plenty of nights out. While dining with friends, Kelli runs into sophomore Sebastian who has a serious playboy reputation, and Kelli finds herself falling under his spell. Meanwhile, public school student Taylor enters the mix and sees Sebastian as her ticket into the tight knit prep school scene.

Anyone who’'s anyone knows about a good party. Jessie’'s best friend Zoe is turning 18 and her party is the talk of the town. But when Jessie asks for PC'’s help with the exclusive Operation Smile charity event, the sparks fly. PC decides to skip Zoe’'s bash and go on a blind date that ends up taking a surprising turn. Meanwhile, Camille takes in all the drama as a love triangle forms in front of her. Sebastian thinks he'’s the king of Zoe'’s party as he courts both Kelli and Taylor. But the tables are turned when Taylor’'s ex-boyfriend Cole shows up and cramps his style. Can a humbled Sebastian make Taylor his queen for the night?

It'’s Winter Break in New York City! Jessie vacations in Florida, but can'’t stop thinking about PC. Meanwhile PC parties around the clock in Cancun, Mexico thinking of no one but himself. Kelli goes to the Hamptons to mourn a death, while Camille and Taylor remain in the City. Cole surprises Taylor after the holidays at her public school, and pressures her to make a decision.

It's all about the future - everyone is thinking about college and what's next. Kelli jumpstarts her singing career and meets with a top voice coach in the city. Taylor is spreading herself thin, trying to balance her love life with her grades and numerous dance classes. Jessie sends out her resume to fashion designers and works on the benefit for Operation Smile. With hopes of getting into Harvard, Camille wants to get involved with Jessie's charity, but when she insults Jessie that dream quickly goes flying. While everyone else is busy with school and extracurriculars, PC is bored by his fabulous life. After going to therapy, PC decides that he needs to do something productive and lands a photography internship. What starts as a regular photo shoot turns into an outrageous adventure with PC in front of the camera and out of his shirt.